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In this study, light emission and absorption spectroscopic measurement techniques were used to investigate the Homogeneous Charge Compression Ignition (HCCI) combustion process in detail, about which there have been many unclear points heretofore. The results made clear the formation behavior and wavelength bands of the chemical species produced during low-temperature reactions. Specifically, with a low level of residual gas, a light emission band was observed from a cool flame in a wavelength range of 370–470 nm. That is attributed to the light emission of formaldehyde (HCHO) produced in the cool-flame reactions. Additionally, it was found that these light emission spectra were no longer observable when residual gas was applied. The light emission spectra of the combustion flame thus indicated that residual gas has the effect of moderating cool-flame reactions.

Homogeneous Charge Compression Ignition (HCCI) combustion offers the advantages of high efficiency and low emissions of pollutants. However, ignition timing control and expansion of the stable operation region are issues remaining to be addressed in this combustion process. Detailed analyses of ignition and combustion characteristics are needed to resolve these issues. HCCI combustion of a low octane number fuel is characterized by two-stage heat release attributed to a cool flame and a hot flame, respectively. In this study, spectroscopic techniques were used to investigate the effect of exhaust gas recirculation (EGR) on ignition and combustion characteristics using a low octane number fuel, which is apt to give rise to a cool flame. The reaction mechanism of a cool flame produces formaldehyde (HCHO). Measurements were made of spontaneous light emission and absorption at wavelengths corresponding to the light emitted at the time HCHO was produced.

Engine oil combined with SPZn instead of ZnDTP shows excellent total base number (TBN) retention in oxidation and NOx gas bubbling tests. The wear resistance of engine oil combined with SPZn was similar to oil combined with ZnDTP in a four-ball test. Prototype engine oils with 1.0 wt% of sulfated ash and 0.04wt%-0.09wt% of SPZn-derived phosphorus were prepared and a JASO valve train wear test was performed on them. The wear resistance of engine oil including SPZn with P = 0.09 wt% was greater than that of engine oil including ZnDTP. This result shows the possibility of reduce the phosphorus in engine oil by using SPZn.

In this study, it was shown that Homogeneous Charge Compression Ignition (HCCI) combustion in a 4-stroke engine, operating under the conditions of a high compression ratio, wide open throttle (WOT) and a lean mixture, could be simulated by raising the compression ratio of a 2-stroke engine. On that basis, a comparison was then made with the characteristics of Active Thermo-Atmosphere Combustion (ATAC), the HCCI process that is usually accomplished in 2-stroke engines under the conditions of a low compression ratio, partial throttle and a large quantity of residual gas. One major difference observed between HCCI combustion and ATAC was their different degrees of susceptibility to the occurrence of cool flames, which was attributed to differences in the residual gas state. It was revealed that the ignition characteristics of these two combustion processes differed greatly in relation to the fuel octane number.

Controlled Autoignition (CAI) combustion processes can be broadly divided between a CAI process that is applied to four-stroke engines and a CAI process that is applied to two-stroke engines. The former process is generally referred to as Homogeneous Charge Compression Ignition (HCCI) combustion and the later process as Active Thermo-Atmosphere Combustion (ATAC). The region of stable engine operation differs greatly between these two processes, and it is thought that the elucidation of their differences and similarities could provide useful information for expanding the operation region of HCCI combustion. In this research, the same two-stroke engine was operated under both the ATAC and HCCI combustion processes to compare their respective combustion characteristics. The results indicated that the ignition timing was less likely to change in the ATAC process in relation to changes in the fuel octane number than it was in the HCCI combustion process.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by direct diesel fuel injection. In this study, the internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the temperature of the mixture before the ignition. It is confirmed that the lean methanol-air mixture of air-fuel ratio between 130 and 18 could be ignited and burned when the back pressure of 80 [kPa] is added. The ignition and combustion characteristics can be improved by the internal EGR, however the engine performance and NOx emission deteriorated.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. The internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the mixture temperature. The test engine was a 4-stroke, single- cylinder direct-injection diesel engine. The cooling system was forced-air cooling and displacement volume was about 211 (cm3). The compression ratio was about 19.9:1. The experiment was made under constant engine speed of 3000 (r/min). The boost pressure was maintained at 101.3 (kPa). Five values of mass flow rate of diesel fuel injection were selected from 0.060 (g/s) to 0.167 (g/s) and five levels of back pressure: 0), 26.7, 53.3, 80.0 and 106.6 (kPa) were selected for the experiment. The effect of internal EGR is varied by the back pressure level.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

In this research, an investigation was made of ion current and OH radical luminescence behavior in the progression from normal combustion to knocking operation. One pair each of an ion probe and a quartz observation window was fitted in the center and on the end of the combustion chamber. The peak values of the ion voltage drop and the OH radical emission intensity both increased as the cylinder head temperature and the cylinder pressure rose. It is possible to understand combustion conditions by analyzing measured waveformes of the ion voltage drop and the OH radical emission intensity.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

The uniform lean gasoline-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. In this study, the internal EGR is add to this ignition method in order to activate the fuel in the mixture before the ignition. It is confirmed that the lean mixture of air-fuel ratio between 150 and 40 could be ignited and burned by this ignition method when the back pressure of 80 [kPa] is added, and the burning period is shorted by internal EGR. However, as the back pressure increases, NOx concentration is increased by the high temperature residual gas.

The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.

The purpose of this research was to obtain a better understanding of engine knocking phenomena. Measurements were made of the behavior of formaldehyde (HCHO), an important intermediate product of cool flame reactions, and of the HCO radical, characterized by distinctive light emission during blue flame reactions. The test engine was operated on a blended fuel (50 RON) of n-heptane and iso-octane. Simultaneous measurements were made of the behavior of HCHO and the OH radical using absorption spectroscopy and of the behavior of HCO and OH radicals using emission spectroscopy. Absorbance spectroscopic measurements revealed behavior thought to correspond to the passage of a cool flame and emission spectroscopic measurements showed behavior thought to correspond to the passage of a blue flame.